Sky blue - the color of the sky changes based on where you are in relation to the sun, and in relation to the horizon. Gurney makes a lot of explanation, but basically you should have at least 4 colors mixed for clear blue sky.
Atmospheric perspective (pg. 176) - the air is illuminated, which means that the further away you are from something, the less bold and clear those colors will be. They will gradually come closer to the color of the sky. "Warm colors advance, cool colors recede".
(http://adamforfang.blogspot.com/2011/11/atmospheric-perspective.html)
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